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Analogous steps are repeated during the propagation stage until polymerization ceases that is, all the monomer is consumed or the reaction is terminated. The use of well-defined initiators combines rapid initiation with high propagation rates and often enables living polymerizations that is, reactions for which there is no termination step to stop chain growth. Thus, precise adjustment of the molecular weight can be accomplished by simply varying the ratio of monomer to initiator. The living character of ROMP enables the synthesis of well-defined, end-functionalized polymers as well as block and graft copolymers with complex architectures and useful functions.

Living ROMP reactions are commonly quenched deliberately through the addition of specific reagents, depending on the type of the initiators used.


  1. research paper chicago style turabian.
  2. Ring-opening Metathesis Polymerization;
  3. Author Corner;

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You may already have access to this content. Sign In. Get AccessScience for your institution. ACS Nano , 4 2 , Christopher J. Faulkner, Remington E. Fischer and G. Macromolecules , 43 3 , Abhinav Rastogi, Marvin Y. Yeh, Nicholas A. Rossi, Donald E. Brooks and Jayachandran N. Biomacromolecules , 11 1 , Macromolecules , 0 proofing DOI: Biomacromolecules , 0 proofing DOI: Yavuz, Gary C. Jensen, David P. Penaloza, Thomas A. Seery, Samuel A. Pendergraph, James F. Rusling and Gregory A. Langmuir , 25 22 , Chemical Reviews , 11 , Langmuir , 25 19 , Paik and Christopher K. Mustafa S. Langmuir , 0 proofing DOI: Chemical Reviews , 0 proofing DOI: The Journal of Physical Chemistry C , 28 , Matthew J.

Allen, Kittikhun Wangkanont, Ronald T.

Supporting Information

Raines and Laura L. Macromolecules , 42 12 , Kizhakkedathu and Donald E. Macromolecules , 42 9 , Macromolecules , 42 7 , Yuquan Zou, Jayachandran N. Accounts of Chemical Research , 41 12 , Wonje Jeong and M. Chemistry of Materials , 20 22 , Macromolecules , 41 19 , Langmuir , 24 17 , Satyabrata Samanta and Jason Locklin. Brad J. Berron,, Evan P. Graybill, and, G. Langmuir , 23 23 , Fei Ren,, Alina K.

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The Organometallic HyperTextBook: Ring-Opening Metathesis Polymerization (ROMP)

Polymer Growth by Functionalized Ruthenium Nanoparticles. Macromolecules , 40 23 , Sarav B. Jhaveri and, Kenneth R. Langmuir , 23 16 , Bokyung Kong,, Jungkyu K. Lee, and, Insung S. Langmuir , 23 12 , Joseph W. Robertson,, Domenic J.

Ring-opening metathesis polymerisation

Tiani, and, Jeanne E. Langmuir , 23 8 , Scherman,, Robert H. Grubbs,, John N. Harb,, Robert C. Davis, and, Matthew R. Chemistry of Materials , 19 7 , The Journal of Physical Chemistry C , 7 , Langmuir , 23 5 , Jianxin Feng,, Stephanie S. Stoddart,, Kanchana A.

Weerakoon, and, Wei Chen. Langmuir , 23 3 , Krishna D. Allara, and, Henry C. Journal of the American Chemical Society , 40 , Matthias Beinhoff,, Anjuli T. Appapillai,, Leah D. Underwood,, Jane E. Frommer, and, Kenneth R. Langmuir , 22 6 , Kenis, and, Ned B.

Mechanism of Ring Opening Metathesis

Langmuir , 22 5 , Teare,, W. Schofield,, R. Garrod, and, J. Langmuir , 21 23 , Jason K. Pontrello,, Matthew J. Allen,, Eric S. Underbakke, and, Laura L. Journal of the American Chemical Society , 42 , Chemistry of Materials , 17 9 , Christopher Love,, Lara A. Estroff,, Jennah K. Kriebel,, Ralph G. Nuzzo, and, George M. Macromolecules , 37 26 , Chemistry of Materials , 16 19 , Amitav Sanyal,, Tyler B. Norsten,, Oktay Uzun, and, Vincent M. Langmuir , 20 14 , Ober,, Geoffrey W.

Coates, and, Carl A. Biomacromolecules , 5 3 , Isaac M. Rutenberg,, Oren A. Journal of the American Chemical Society , 13 , Li,, M. Swihart, and, E. Langmuir , 20 5 , Ford,, Daniel E. Resasco, and, Jose E. Journal of the American Chemical Society , 1 , Fuierer, and, Christopher B. Yu,, E. Kang, and, K. Neoh, , Shiping Zhu. The Journal of Physical Chemistry B , 37 , Journal of the American Chemical Society , 31 , Majad Khan and, Wilhelm T. Macromolecules , 36 14 , Yoshiko Harada,, Gregory S. Girolami, and, Ralph G. Langmuir , 19 12 , Timothy A. Germack,, Erik C.

Hagberg,, Valerie V. Sheares,, Craig J.


  • Pure and Applied Chemistry.
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  • "SURFACE ENGINEERING AND MONOMER DESIGN FOR LIGHT-MEDIATED RING OPENING" by Ishan A. Fursule.