Analogous steps are repeated during the propagation stage until polymerization ceases that is, all the monomer is consumed or the reaction is terminated. The use of well-defined initiators combines rapid initiation with high propagation rates and often enables living polymerizations that is, reactions for which there is no termination step to stop chain growth. Thus, precise adjustment of the molecular weight can be accomplished by simply varying the ratio of monomer to initiator. The living character of ROMP enables the synthesis of well-defined, end-functionalized polymers as well as block and graft copolymers with complex architectures and useful functions.
Living ROMP reactions are commonly quenched deliberately through the addition of specific reagents, depending on the type of the initiators used.
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The Organometallic HyperTextBook: Ring-Opening Metathesis Polymerization (ROMP)
Polymer Growth by Functionalized Ruthenium Nanoparticles. Macromolecules , 40 23 , Sarav B. Jhaveri and, Kenneth R. Langmuir , 23 16 , Bokyung Kong,, Jungkyu K. Lee, and, Insung S. Langmuir , 23 12 , Joseph W. Robertson,, Domenic J.
Ring-opening metathesis polymerisation
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Mechanism of Ring Opening Metathesis
Langmuir , 22 5 , Teare,, W. Schofield,, R. Garrod, and, J. Langmuir , 21 23 , Jason K. Pontrello,, Matthew J. Allen,, Eric S. Underbakke, and, Laura L. Journal of the American Chemical Society , 42 , Chemistry of Materials , 17 9 , Christopher Love,, Lara A. Estroff,, Jennah K. Kriebel,, Ralph G. Nuzzo, and, George M. Macromolecules , 37 26 , Chemistry of Materials , 16 19 , Amitav Sanyal,, Tyler B. Norsten,, Oktay Uzun, and, Vincent M. Langmuir , 20 14 , Ober,, Geoffrey W.
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- "SURFACE ENGINEERING AND MONOMER DESIGN FOR LIGHT-MEDIATED RING OPENING" by Ishan A. Fursule.